Photographic Formulae and Notes 10/8/18
(C) b-wtechnik.pp7.uk
The objective is to :
1. Use low cost readily available chemicals equivalent to photographic grades
where required.
Most of the chemicals below are essentially common food
grade E numbers.
2. Use simple formulae that have excellent keeping properties and are easy and
quick to prepare
3. Have a minimum effect on the environment
The approximate costs shown relate to the purchase of small quantities i.e.
500g - 1000g except for
developing agents which assume 100g quantities.
UNLESS STATED, ALL SOLUTIONS ARE TO MAKE 1 litre
Water Softeners (Stops water hardness precipitating out in alkaline solutions)
W001 EDTA Softened water.
Disodium EDTA | 7.5g |
Sodium hydroxide | 1.05g |
Tap Water | 5 litres |
approximate cost £p / litre | 5.0 |
pH should be close to 7 therefore will not upset the pH of weak developers.
W002 STPP Softened water
Sodium tripolyphosphate STPP | 7.5g |
Tap Water | 5 litres |
approximate cost £p / litre | 2.5 |
May be used for the preparation of all other solutions, however, after a
period of time,
it loses its effectiveness in alkaline solutions and so should only be used in
one shot applications.
STPP on its own increases the alkalinity of the solution which may be a problem
in weak developers.
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Use softened water for the preparation of all other
processing
solutions in particular alkaline ones.
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FD003 ID11 Fine Grain Developer
Metol | 2.0g |
Hydroquinone | 5.0g |
Sodium sulphite | 100g |
Sodium tetraborate 8H2O (Borax) | 2.0g |
approximate cost £p / litre | 108 |
The standard high sulphite fine grain developer with no speed loss.
Development times are often too short with stock solution.
Can be used 1 + 1 dilution with little degradation.
FD004 ID11b, Buffered Version
Metol | 2.0g |
Hydroquinone | 5.0g |
Sodium sulphite | 100g |
Sodium tetraborate 8H2O (Borax) | 8.0g |
Boric acid | 3.6g |
approximate cost £p / litre | 130 |
Preferred for use at 1 + 1 dilution while maintaining film characteristics.
Development times are in between Stock and 1+1 ID11.
Maintains macro and micro pH during development.
PD005 Dektol Paper Developer
Metol | 3.1g |
Hydroquinone | 12g |
Sodium sulphite | 45g |
Sodium carbonate | 80g |
Potassium bromide | 1.9g |
approximate cost £p / litre | 260 |
Use at either 1 + 2 or 1 + 3 dilution.
S006 A Buffered Citric Acid Stop Bath
Citric acid | 4.0g |
Trisodium citrate 2H2O | 6.0g |
Sodium (or potassium) metabisulphite | 1.0g |
approximate cost £p / litre | 11 |
Citric acid is 15 times stronger than acetic acid which will give a pH less
than 4 on its own.
If this is a concern, add the sodium citrate. The metabisulphite suppresses
growths of organisms.
Without it black things float on the top after a few weeks. This is meant as a
one shot solution anyway.
The choice is yours.
S007 A Buffered Neutral Stop Bath
Disodium phosphate | 4.0g |
Monopotassium dihydrogen phosphate | 3.8g |
approximate cost £p / litre | 11 |
This will arrest film development as quickly as a normal acid stop bath and
is intended to
be used with alkaline or neutral fixers. Use once only. Unlike citric acid
types as above, you
can make up large quantities and store it without problems even without
sulphites.
Target pH is 6.9 - 7.
F008 Buffered Alkaline Fixer
Sodium thiosulphate 5H2O | 250g |
Ammonium chloride | 40g |
Sodium sulphite | 15g |
Disodium phosphate | 15g |
Monopotassium dihydrogen phosphate | 6.0g |
approximate cost £p / litre | 160 |
Use undiluted. Target pH is 7.6 and the addition of ammonium chloride gives
a fast fixing time.
Delta 100 clears in about 1 minute. Unlike acid fixers, this formulation lasts
at least 2 years with no degradation.
S009 A Simple Stop Bath
Sodium or potassium metabisulphite | 5.0g |
approximate cost £p / litre | 4 |
This is a one shot stop bath with a pH of about 5. The only disadvantage is
a slight smell of
sulphur dioxide. When prepared in bulk and stored for a long time, there is no
possibility
of growths in the solution